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Polysulfone and zirconia composite separators for alkaline water electrolysis

Li XU, Wei LI, Yan YOU, Shaoxing ZHANG, Yingchun ZHAO

《化学科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 154-161 doi: 10.1007/s11705-013-1331-8

摘要： The novel composite separators composed of polysulfone and zirconia were prepared by phase inversion precipitation technique. This technique allows pre-evaporation time and extraction temperature to be varied in order to obtain optimal performances of the separators. In order to evaluate practical applicability of those composite separators, a small-scale electrolysis experimental apparatus was used to investigate the changes of cell voltage, gas purity and separator stability. The results revealed a decreased cell voltage compared to the conventional asbestos separators, and the gas purity and separator stability met the requirements for industrial use.

关键词： phase inversion     separator     alkaline water electrolysis     mechanical and chemical stability    

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Regulating surface chemistry of separator with LiF for advanced Li-S batteries

《能源前沿（英文）》 2022年 第16卷 第4期   页码 601-606 doi: 10.1007/s11708-021-0759-7

摘要： Lithium-sulfur (Li-S) batteries have attracted intensive attention owing to their ultrahigh theoretical energy density. Nevertheless, the practical application of Li-S batteries is prevented by uncontrollable shuttle effect and retarded reaction kinetics. To address the above issues, lithium fluoride (LiF) was employed to regulate the surface chemistry of routine separator. The functional separator demonstrates a great ability to suppress active S loss and protect lithium anode. This work provides a facile strategy for the development of advanced Li-S batteries.

关键词： Li-S batteries     LiF     functional separator    

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Experimental investigation on oil-gas separator of air-conditioning systems

Dianbo XIN,Shuliang HUANG,Song YIN,Yuping DENG,Wenqiang ZHANG

《能源前沿（英文）》 2019年 第13卷 第2期   页码 411-416 doi: 10.1007/s11708-017-0447-9

摘要： The oil-return system plays an important role in the variable refrigerant flow (VRF) systems because it ensures the reliable operation of the VRF systems. The oil-gas separator is the most essential component of the oil-return system, and the separation efficiency of the separator directly influences the performance of the VRF systems. Therefore, in this paper, a test rig was built to measure the oil discharge ratio of the compressor and the separation efficiency of the oil-gas separator. A sound velocity transducer was used to measure the oil mass concentration instantaneously, because the sound velocity was changed with the mass ratio of oil to refrigerant. The separation efficiency of the separator could be obtained by comparing the mass fraction of oil to refrigerant before and after the separator was connected to the system.

关键词： variable refrigerant flow system     oil-gas separator     separation efficiency    

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Modeling the gas flow in a cyclone separator at different temperature and pressure

Gujun WAN, Guogang SUN, Cuizhi GAO, Ruiqian DONG, Ying ZHENG, Mingxian SHI

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 498-505 doi: 10.1007/s11705-010-0502-0

摘要： The gas flow field in a cyclone separator, operated within a temperature range of 293 K – 1373 K and a pressure range of 0.1 – 6.5 MPa, has been simulated using a modified Reynolds-stress model (RSM) on commercial software platform FLUENT 6.1. The computational results show that the temperature and pressure significantly influence the gas velocity vectors, especially on their tangential component, in the cyclone. The tangential velocity decreases with an increase in temperature and increases with an increase in pressure. This tendency of the decrease or increase, however, reduces gradually when the temperature is above 1000 K or the pressure goes beyond 1.0 MPa. The temperature and pressure have a relatively weak influence on the axial velocity profiles. The outer downward flow rate increases with a temperature increase, whereas it decreases with a pressure increase. The centripetal radial velocity is strong in the region of 0 – 0.25 below the vortex finder entrance, which is named as a short-cut flow zone in this study. Based on the simulation results, a set of correlations was developed to calculate the combined effects of temperature and pressure on the tangential velocity, the downward flow rate in the cyclone and the centripetal radial velocity in the short-cut flow region underneath the vortex finder.

关键词： cyclone separator     high temperature     high pressure     flow field     numerical simulation    

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Using crosslinked polyvinyl alcohol polymer membrane as a separator in the microbial fuel cell

Yanping HOU, Kaiming LI, Haiping LUO, Guangli LIU, Renduo ZHANG, Bangyu QIN, Shanshan CHEN

《环境科学与工程前沿（英文）》 2014年 第8卷 第1期   页码 137-143 doi: 10.1007/s11783-013-0534-z

摘要： Separator between anode and cathode is an essential part of the microbial fuel cell (MFC) and its property could significantly influence the system performance. In this study we used polyvinyl alcohol (PVA) polymer membrane crosslinked with sulfosuccinic acid (SSA) as a new separator for the MFC. The highest power density of 759±4 mW·m was obtained when MFC using the PVA membrane crosslinked with 15% of SSA due to its desirable proton conductivity (5.16 × 10 S·cm ). The power density significantly increased to 1106±30?mW·m with a separator-electrode-assembly configuration, which was comparable with glass fiber (1170±46?mW·m ). The coulombic efficiencies of the MFCs with crosslinked PVA membranes ranged from 36.3% to 45.7% at a fix external resistance of 1000 ?. The crosslinked PVA membrane could be a promising alternative to separator materials for constructing practical MFC system.

关键词： microbial fuel cell     crosslinked polyvinyl alcohol (PVA) membrane     separator material     power generation     coulombic efficiency    

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Aggravation of membrane fouling and methane leakage by a three-phase separator in an external anaerobic

Chao Pang, Chunhua He, Zhenhu Hu, Shoujun Yuan, Wei Wang

《环境科学与工程前沿（英文）》 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1131-6

摘要：

The existence of three-phase separator did not affect COD removal in the EAnCMBR.

The existence of three-phase separator aggravated methane leakage of EAnCMBR.

The existence of three-phase separator aggravated membrane fouling rate of EAnCMBR.

Start-up of EAnCMBR equipped three-phase separator was slightly delayed.

关键词： Anaerobic membrane bioreactor     Three-phase separator     Membrane fouling     Methane leakage     Sludge property    

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A comparative study on polypropylene separators coated with different inorganic materials for lithium-ion batteries

Linghui Yu, Jiansong Miao, Yi Jin, Jerry Y.S. Lin

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 346-352 doi: 10.1007/s11705-017-1648-9

摘要： Coating commercial porous polyolefin separators with inorganic materials can improve the thermal stability of the polyolefin separators and hence improve the safety of lithium-ion batteries. Several different inorganic materials have been studied for the coating. However, there lacks a study on how different inorganic materials affect the properties of separators, in terms of thermal stability and cell performance. Herein, we present such a study on coating a commercial polypropylene separator with four inorganic materials, i.e., Al O , SiO , ZrO and zeolite. All inorganic coatings have improved thermal stability of the separators although with differences. The coating layers add 28%–45% of electrical resistance compared with the pure polypropylene separator, but all the cells prepared with the coated polypropylene separators have the same electrical chemical performance as the uncoated separator in terms of rate capability and capacities at different temperatures.

关键词： lithium-ion battery     battery safety     composite separator     porosity     tortuosity    

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Gas-solids separation model of a novel FCC riser terminator device: super short quick separator (SSQS

LU Chunxi, LI Ruxin, SHI Mingxian, LIU Xiancheng

《化学科学与工程前沿（英文）》 2008年 第2卷 第4期   页码 462-467 doi: 10.1007/s11705-008-0068-2

摘要： The gas flow field and the separation efficiency of a novel fluid catalytic cracking (FCC) riser terminal device, named as Super Short Quick Separator (SSQS), were studied. On the basis of above investigations, a section-lateral-mixing separation model was proposed, which included both the effect of inertia and structure of gas outlet on particles capture. After final modification, the results predicted with this model could be in good agreement with the cold experimental data. According to this model, the separation efficiency of SSQS is mainly influenced by the difference between the arc radius and the center pipe radius as well as the magnitude of particle tangential velocity.

关键词： catalytic cracking     separation efficiency     tangential velocity     agreement     magnitude    

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Technological development and engineering applications of novel steel-concrete composite structures

Jianguo NIE, Jiaji WANG, Shuangke GOU, Yaoyu ZHU, Jiansheng FAN

《结构与土木工程前沿（英文）》 2019年 第13卷 第1期   页码 1-14 doi: 10.1007/s11709-019-0514-x

摘要：

In view of China’s development trend of green building and building industrialization, based on the emerging requirements of the structural engineering community, the development and proposition of novel resource-saving high-performance steel-concrete composite structural systems with adequate safety and durability has become a kernel development trend in structural engineering. This paper provides a state of the art review of China’s cutting-edge research and technologies in steel-concrete composite structures in recent years, including the building engineering, the bridge engineering and the special engineering. This paper summarizes the technical principles and applications of the long-span bi-directional composite structures, the long-span composite transfer structures, the comprehensive crack control technique based on uplift-restricted and slip-permitted (URSP) connectors, the steel plate concrete composite (SPCC) strengthen technique, and the innovative composite joints. By improving and revising traditional structure types, the comprehensive superiority of steel-concrete composite structures is well elicited. The research results also indicate that the high-performance steel-concrete composite structures have a promising popularizing prospect in the future.

关键词： high-performance composite structure     bi-directional composite     composite transfer     uplift-restricted and slip-permitted connectors     steel plate concrete composite strengthen    

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Deep eutectic solvent inclusions for high- composite dielectric elastomers

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 996-1002 doi: 10.1007/s11705-022-2138-2

摘要： Recent advances in novel electroactive devices have placed new requirements on material development. High-performance dielectric elastomers with good mechanical stretchability and high dielectric constant are under high demand. However, the current strategy for fabricating these materials suffers from high cost or low thermal stability, which greatly hinders large-scale industrial production. Herein, we have successfully developed a novel strategy for improving the dielectric constant of polymeric elastomers via deep eutectic solvent inclusion by taking advantage of the low cost, convenient and environmentally benign synthesis process and high ionic conductivity from deep eutectic solvents. The as-prepared composite elastomers showed good stretchability and a greatly enhanced dielectric constant with a negligible increase in dielectric dissipation. Moreover, we have proven the universality of our strategy by using different types of deep eutectic solvents. It is believed that low-cost, easy-synthesis and environmentally friendly deep eutectic solvents including composite elastomers are highly suitable for large-scale industrial production and can greatly broaden the application fields of dielectric elastomers.

关键词： composite materials     deep eutectic solvent     dielectric elastomer     high dielectric constant    

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An antibiotic composite electrode for improving the sensitivity of electrochemically active biofilm biosensor

《环境科学与工程前沿（英文）》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1518-7

摘要：

• Antibiotic azithromycin employed in graphite electrode for EAB biosensor.

关键词： AZM@GP composite electrode     EAB-biosensor     Water quality early-warning    

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Structural optimization of filament wound composite pipes

Roham RAFIEE; Reza SHAHZADI; Hossein SPERESP

《结构与土木工程前沿（英文）》 2022年 第16卷 第8期   页码 1056-1069 doi: 10.1007/s11709-022-0868-3

摘要： An optimization procedure is developed for obtaining optimal structural design of filament wound composite pipes with minimum cost utilized in pressurized water and waste-water pipelines. First, the short-term and long-term design constraints dictated by international standards are identified. Then, proper computational tools are developed for predicting the structural properties of the composite pipes based on the design architecture of layers. The developed computational tools are validated by relying on experimental analysis. Then, an integrated design-optimization process is developed to minimize the price as the main objective, taking into account design requirements and manufacturing limitations as the constraints and treating lay-up sequence, fiber volume fraction, winding angle, and the number of total layers as design variables. The developed method is implemented in various case studies, and the results are presented and discussed.

关键词： composite pipes     optimization     experimental validation     computational modeling     filament winding    

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Progressive failure analysis of notched composite plate by utilizing macro mechanics approach

《结构与土木工程前沿（英文）》 2021年 第15卷 第3期   页码 623-642 doi: 10.1007/s11709-021-0726-8

摘要： In this study, gradual and sudden reduction methods were combined to simulate a progressive failure in notched composite plates using a macro mechanics approach. Using the presented method, a progressive failure is simulated based on a linear softening law prior to a catastrophic failure, and thereafter, sudden reduction methods are employed for modeling a progressive failure. This combination method significantly reduces the computational cost and is also capable of simultaneously predicting the first and last ply failures (LPFs) in composite plates. The proposed method is intended to predict the first ply failure (FPF), LPF, and dominant failure modes of carbon/epoxy and glass/epoxy notched composite plates. In addition, the effects of mechanical properties and different stacking sequences on the propagation of damage in notched composite plates were studied. The results of the presented method were compared with experimental data previously reported in the literature. By comparing the numerical and experimental data, it is revealed that the proposed method can accurately simulate the failure propagation in notched composite plates at a low computational cost.

关键词： progressive failure     notched composite plate     Hashin failure criterion     macro mechanics approach     finite element method    

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Bending and rotational behaviour of semi-continuous composite beams

WANG Jingfeng, LI Guoqiang

《结构与土木工程前沿（英文）》 2008年 第2卷 第2期   页码 116-122 doi: 10.1007/s11709-008-0015-9

摘要： Stresses and deflections were measured in various semi-continuous composite beams. The bending and rotational capacities of the composite connections were measured in terms of beam curvatures and deflections by using two full-scale semi-rigid composite frames with monotonic loadings. The effect of semi-rigid connections on the performance of composite beams with various loadings was compared with predictions and codes. The tests show that the semi-continuous composite beams are more economic and effective than the simple or continuous composite beams. The semi-rigid connections affect the bending capacities and beam deflections, so the connection behavior should be considered in the design of composite beams. Yielding analysis of the steel beam bottom flange has some influence on the deflection calculation of composite beams.

关键词： rotational     effective     deflection calculation     semi-continuous composite     full-scale semi-rigid    

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Experimental study on flexural behavior of ECC/RC composite beams with U-shaped ECC permanent formwork

Zhi QIAO, Zuanfeng PAN, Weichen XUE, Shaoping MENG

《结构与土木工程前沿（英文）》 2019年 第13卷 第5期   页码 1271-1287 doi: 10.1007/s11709-019-0556-0

摘要： To enhance the durability of a reinforced concrete structure, engineered cementitious composite (ECC), which exhibits high tensile ductility and good crack control ability, is considered a promising alternative to conventional concrete. However, broad application of ECC is hindered by its high cost. This paper presents a new means to address this issue by introducing a composite beam with a U-shaped ECC permanent formwork and infill concrete. The flexural performance of the ECC/RC composite beam has been investigated experimentally with eight specimens. According to the test results, the failure of a composite beam with a U-shaped ECC formwork is initiated by the crushing of compressive concrete rather than debonding, even if the surface between the ECC and the concrete is smooth as-finished. Under the same reinforcement configurations, ECC/RC composite beams exhibit increases in flexural performance in terms of ductility, load-carrying capacity, and damage tolerance compared with the counterpart ordinary RC beam. Furthermore, a theoretical model based on the strip method is proposed to predict the moment-curvature responses of ECC/RC composite beams, and a simplified method based on the equivalent rectangular stress distribution approach has also evolved. The theoretical results are found to be in good agreement with the test data.

关键词： engineered cementitious composite (ECC)     durability     ECC/RC composite beam     permanent formwork     flexural performance     theoretical method    

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标题 作者 时间 类型 操作

Polysulfone and zirconia composite separators for alkaline water electrolysis

Li XU, Wei LI, Yan YOU, Shaoxing ZHANG, Yingchun ZHAO

期刊论文

Regulating surface chemistry of separator with LiF for advanced Li-S batteries

期刊论文

Experimental investigation on oil-gas separator of air-conditioning systems

Dianbo XIN,Shuliang HUANG,Song YIN,Yuping DENG,Wenqiang ZHANG

期刊论文

Modeling the gas flow in a cyclone separator at different temperature and pressure

Gujun WAN, Guogang SUN, Cuizhi GAO, Ruiqian DONG, Ying ZHENG, Mingxian SHI

期刊论文

Using crosslinked polyvinyl alcohol polymer membrane as a separator in the microbial fuel cell

Yanping HOU, Kaiming LI, Haiping LUO, Guangli LIU, Renduo ZHANG, Bangyu QIN, Shanshan CHEN

期刊论文

Aggravation of membrane fouling and methane leakage by a three-phase separator in an external anaerobic

Chao Pang, Chunhua He, Zhenhu Hu, Shoujun Yuan, Wei Wang

期刊论文

A comparative study on polypropylene separators coated with different inorganic materials for lithium-ion batteries

Linghui Yu, Jiansong Miao, Yi Jin, Jerry Y.S. Lin

期刊论文

Gas-solids separation model of a novel FCC riser terminator device: super short quick separator (SSQS

LU Chunxi, LI Ruxin, SHI Mingxian, LIU Xiancheng

期刊论文

Technological development and engineering applications of novel steel-concrete composite structures

Jianguo NIE, Jiaji WANG, Shuangke GOU, Yaoyu ZHU, Jiansheng FAN

期刊论文

Deep eutectic solvent inclusions for high- composite dielectric elastomers

期刊论文

An antibiotic composite electrode for improving the sensitivity of electrochemically active biofilm biosensor

期刊论文

Structural optimization of filament wound composite pipes

Roham RAFIEE; Reza SHAHZADI; Hossein SPERESP

期刊论文

Progressive failure analysis of notched composite plate by utilizing macro mechanics approach

期刊论文

Bending and rotational behaviour of semi-continuous composite beams

WANG Jingfeng, LI Guoqiang

期刊论文

Experimental study on flexural behavior of ECC/RC composite beams with U-shaped ECC permanent formwork

Zhi QIAO, Zuanfeng PAN, Weichen XUE, Shaoping MENG

期刊论文